Impact of Changes in Redox Conditions on Leaching of Some Elements from MSW Fly Ash     

Lallan Prasad Gupta    Hodaka Kawahata    Mio Ltakeuchi  Hidekazu Ohta  Yoshiro Ono 《Resource Geology》2006,56(2):191-196

Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions.  相似文献   

Deep seismic reflection study over the Vindhyans of Rajasthan: Implications for geophysical setting of the basin     

B Rajendra Prasad  V Vijaya Rao 《Journal of Earth System Science》2006,115(1):135-147

This paper presents results of high-resolution deep seismic reflection profiling of the Proterozoic Vindhyan basin of the Rajasthan area along the Chandli-Bundi-Kota-Kunjer profile. Seismic images have been used to estimate the thickness of Vindhyan strata as well as to understand the tectonic framework of the basin. The results are constrained by gravity, magnetic and magnetotelluric data. The study reveals gentle SE-dipping reflection bands representing the Vindhyan strata. The seismic sections depict gradual thickening of the Vindhyan succession towards southeast from Bundi. The velocities of the upper and lower Vindhyans are identified as 4.6-4.8 km/s and 5.1-5.3 km/s. The NW limit of the Vindhyan basin is demarcated by the Great Boundary Fault (GBF) that manifests as a 30 km wide NW dipping thrust fault extending to a depth of 30 km.  相似文献   

应用等效纬度-海拔模型进行地温及多年冻土制图   总被引：2，自引：2，他引：2  

KenjiYoshikawa PrasadGogineni 《冰川冻土》2002,24(5):526-531

This research presents a method for permafrost mapping in discontinuous permafrost regions based on equivalent latitude/elevation concept in interior Alaska. In winter months, study site has a strong temperature inversion in air up to 700 m elevation. Air temperature data and the effects of slope, aspect and elevation were used to create an equivalent latitude/elevation model. This model was well correlated with mean annual surface temperature (0.79). In this watershed, the thawing index (It≈1 400 ℃*days) at the ground surface and snow depth do not vary greatly from south facing to north facing slopes. The primary controlled factor that determines the mean annual surface temperature was the winter surface temperature. The permafrost stability is effectively controlled by the freezing index. We determined 37.5% of Caribou-Poker Creeks Research Watershed has unstable or thawing permafrost. At least 2.1% of the permafrost in this watershed may have disappeared in the last 90 years due to climate warming. This method makes it possible to evaluate the permafrost stability in the present, past and future.  相似文献   

Promoting social justice and conserving montane forest environments: a case study of Nepal's community forestry programme   总被引：1，自引：0，他引：1  

Netra Prasad Timsina 《The Geographical journal》2003,169(3):236-242

This paper analyses participatory forest policy and the ways it has influenced the relationships between people as it relates to the forest resource management. This case study was conducted in the middle hills of Nepal, and information was collected through direct observation, individual interviews, group discussion and secondary information analysis. It substantiates a few examples of how the community forestry programme can be used as a means to promote the participation of the women, the poor and dalit (untouchables) in forest resource management, as well as enhancing social justice and improving the forest resources in their locality. However, it also demonstrates that though the community forestry programme has a positive impact, it faces several constraints and challenges. The local Forest User Group is controlled by a few élites making the poor and disadvantaged vulnerable to further marginalization. The results of the case study strongly indicate that community forestry processes must address the political, economic and social needs of the forest users, and also provide a neutral platform on which the poor can present their cases.  相似文献   

Elastic properties of dry clay mineral aggregates, suspensions and sandstones   总被引：2，自引：0，他引：2  

Tiziana Vanorio  Manika Prasad  Amos Nur 《Geophysical Journal International》2003,155(1):319-326

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Two and Half Dimensional Simulation of Ridge Effects on the Ground Motion Characteristics     

J. P. Narayan  P. V. Prasad Rao 《Pure and Applied Geophysics》2003,160(8):1557-1571

— Seismic responses of weathered and non-weathered ridge models were simulated to study the ridge effects on the ground motion characteristics. The range of ridge slope from 19.98° to 45° was considered to produce a possible set of generalized results. 2.5-D modeling based on parsimonious staggered grid approximation of elastodynamic wave equations was adopted in simulations. Computed results reveal an increase of amplitude of incoming waves with both elevation and the slope of the ridge. Further, the characteristics of surface waves are highly ridge slope dependent. The analysis of responses of weathered and non-weathered ridge models reveals that ridge has caused a strong generation of surface waves near its top. The surface waves are not dominating on the top of the ridge but at some lower elevation. The increase of weathering of ridge further intensified the ridge effect. Analysis in frequency domain, based on spectral ratio method, does not indicate any pattern in the spectral amplification factor and is very much sensitive to slope, source focal mechanism and location. However, on an average there is a continuous decrease of amplification with slope in the vertical component and increase in the transverse component, and it is increasing in the radial component up to slope =38.0° and thereafter decreasing.  相似文献   

A quantitative study of the energy release in the aftershocks of the Bhuj earthquake, 2001, India, using Lg phase     

G. Jayachandran  M.M. Abdul RazakA.G.V. Prasad  E. Unnikrishnan 《Physics of the Earth and Planetary Interiors》2003,138(2):131-145

The devastating earthquake on 26 January 2001 at Bhuj, India, resulted in large-scale death and destruction of properties of several million US dollars. The moment magnitude of the earthquake was 7.7 and its maximum focal intensity exceeded X in MM scale. The rate of aftershocks of this earthquake, recorded at Gauribidanur seismic array station (GBA), shows a monotonic decay with time superposed with oscillations. For the Indian continent the Lg phase is a prominent arrival at regional distances. The estimate of Lg amplitude is obtained by optimally fitting the Lg wave train to a exponential decay curve. The logarithm of these amplitudes and logarithm of root mean square (rms) value of actual amplitudes of the Lg are calibrated with USGS m_b to create a local m_bLg magnitude scale. The energy released from these aftershocks is calculated from the rms value of Lg phase. The plot of cumulative energy release with time follows the power law of the form t^p, superposed with oscillations. The exponent of the power law, p, is estimated both by a time-window scanning method and by an interpolation method. The value of p is 0.434 for time-window scanning method and 0.432 for the interpolation method. The predominant periods found in the oscillatory part of the cumulative energy, obtained by differencing the observed from the power law fit, are 10.6, 7.9, 5.4, 4.6 and 3.5 h for time-window scanning method. The corresponding periods for interpolation method are 13.4, 11.5, 7.4, 4.2, 3.5, 2.6 and 2.4 h.  相似文献   

Characteristics of VHF radiowave scintillations over a solar cycle (1983–1993) at a low-latitude station: Waltair (17.7°N, 83.3°E)     

P. V. S. Rama Rao  P. T. Jayachandran  P. Sri Ram  B. V. Ramana Rao  D. S. V. V. D. Prasad  K. K. Rose 《Annales Geophysicae》1997,15(6):729-733

The characteristics of VHF radiowave scintillations at 244 MHz (FLEETSAT) during a complete solar cycle (1983–93) at a low-latitude station, Waltair (17.7°N, 83.3°E), are presented. The occurrence of night-time scintillations shows equinoctial maxima and summer minima in all the epochs of solar activity, and follows the solar activity. The daytime scintillation occurrence is negatively correlated with the solar activity and shows maximum occurrence during the summer months in a period of low solar activity. The occurrence of night-time scintillations is inhibited during disturbed days of high solar activity and enhanced during low solar activity.  相似文献   

Temperature and pH Dependence of Some Metals Leaching from Fly Ash of Municipal Solid Waste     

Lallan Prasad Gupta    Hodaka Kawahata    Mio Takeuchi  Hidekazu Ohta  Yoshiro Ono 《Resource Geology》2005,55(4):357-372

Abstract. Municipal solid waste combustion leads to concentration of various metals in the solid residue (fly ash) remaining after combustion. These metals pose serious environmental hazard and require proper handling and monitoring in order to control their harmful effects. Leachability of some metals from fly ash was examined in fly ash and Milli-Q water mixture (liquid-to-solid ratio, 100) under various temperature and pH conditions in the laboratory. The leaching experiments conducted for 24 hours showed that pH was generally more important than temperature in controlling the amount of metals leached out of the fly ash. However, at a given pH, rise in temperature led to different degree of (usually one to two fold) enhanced or reduced leaching of metals. Owing to amphoteric nature of oxides of Al, Cr, Pb and Zn, these metals often yielded typical pattern of increase and decrease in their concentrations with change in pH. The extent of leaching of Cr and Pb in our experiments suggests that decrease of pH to acidic range in the case of Pb and to neutral to acidic range for Cr over a long period of storage of fly ash at solid waste dumping site may facilitate leaching of these metals from fly ash, leading to contamination of groundwater to the level that exceeds beyond the level permitted by the environmental laws.  相似文献   

Perceptive of the pyroxene-bearing micrometeorites and their relation to chondrites          下载免费PDF全文

N. G. Rudraswami  D. Fernandes  Agnelo De Araujo  M. Shyam Prasad  S. Taylor 《Meteoritics & planetary science》2018,53(10):2035-2050

We studied 149 pyroxenes from 69 pyroxene-bearing micrometeorites collected from deep-sea sediments of the Indian Ocean and South Pole Water Well at Antarctica, Amundsen-Scott South Pole station. The minor elements in pyroxenes from micrometeorites are present in the ranges as follows: MnO ~0.0–0.4 wt%, Al₂O₃ ~0.0–1.5 wt%, CaO ~0.0–1.0 wt%, Cr₂O₃ ~0.3–0.9 wt%, and FeO ~0.5–4 wt%. Their chemical compositions suggest that pyroxene-bearing micrometeorites are mostly related to precursors from carbonaceous chondrites rather than ordinary chondrites. The Fe/(Fe+Mg) ratio of the pyroxenes and olivines in micrometeorites shows similarities to carbonaceous chondrites with values lying between 0 and 0.2, and those with values beyond this range are dominated by ordinary chondrites. Atmospheric entry of the pyroxene-bearing micrometeorites is expected to have a relatively low entry velocity of <16 km s⁻¹ and high zenith angle (70–90°) to preserve their chemical compositions. In addition, similarities in the pyroxene and olivine mineralogical compositions between carbonaceous chondrites and cometary particles suggest that dust in the solar system is populated by materials from different sources that are chemically similar to each other. Our results on pyroxene chemical compositions reveal significant differences with those from ordinary chondrites. The narrow range in olivine and pyroxene chemical compositions are similar to those from carbonaceous chondrites, and a small proportion to ordinary chondrites indicates that dust is largely sourced from carbonaceous chondrite-type bodies.  相似文献